Risk factors and loss prevention

RF Temperature
Pistachio nuts require particular temperature, humidity/moisture and ventilation conditions for this reason, precise details should always be obtained from the consignor as to the travel temperature to be maintained.

The stated travel temperature of 0^°C is the ideal temperature for achieving the longest possible storage life, but higher travel temperatures (5 - 25^°C) are feasible (depending upon the duration of the voyage), so this product need not necessarily be carried as chilled goods.

Temperatures > 30^°C should not prevail for a long period, as respiration of the cargo is otherwise promoted.

Pistachio nuts should not be stowed near heat sources (engine room bulkhead, heated tanks). Above all, they must not be exposed to sunlight, as these results in impaired flavor.

RF Humidity/Moisture
Pistachio nuts require particular temperature, humidity/moisture and ventilation conditions

Designation	Humidity/water content	Source
Relative humidity	65 - 70%	[1]
Water content	6%	[1]
	4%	[2]
	6%	[5]
Maximum equilibrium moisture content	65%	[1]

 Precise details should be obtained from the consignor as to the relative humidity to be maintained during the voyage.

Pistachio nuts must be protected from all forms of moisture (seawater, rain and condensation water), since there is otherwise an increased risk of mold, rot and rancidity. They rapidly absorb moisture from the air and the flavor becomes insipid.

Sodden packing drums or bags must be rejected as seawater, rain and condensation water

Promote hydrolytic/enzymatic fat cleavage, which leads to self-heating as a result of increased respiration.

RF ventilation
Pistachio nuts require particular temperature, humidity/moisture and ventilation conditions.

Recommended ventilation conditions: air exchange rate: at least 10 changes/hour (airing)

RF biotic activity
Pistachio nuts display 2nd order

They are living organs in which respiration processes predominate, because their supply of new nutrients has been cut off by separation from the parent plant.

Care of the cargo during the voyage must be aimed at keeping decomposition processes at the lowest possible level, so as to keep within limits any losses in quality caused by the emission of CO₂, heat and water vapor.

RF gases
In pistachio nuts (particularly when fresh), metabolic processes continue even after harvesting. They absorb oxygen and excrete carbon dioxide (CO₂).

If ventilation has been inadequate (frost) or has failed owing to a defect, life-threatening CO₂ concentrations or O₂ shortages may arise. Therefore, before anybody enters the hold, it must be ventilated and a gas measurement carried out. The TLV for CO₂ concentration is 0.49 vol. %.

RF self-heating / spontaneous combustion
Oil content:
● 45 - 54% [1]
● 55% [2]


Because of their tendency to self-heating, pistachio nuts may behave like substances from Class 4.2 of the IMDG Code.

Excessive stack pressure results in self-heating. Oils which have accumulated in the jute packaging fabric encourage this behavior.

Pistachio nuts, especially pistachio kernels, should not be stowed together with fibers/fibrous materials as oil-soaked fibers may promote self-heating/spontaneous combustion of the cargo.

As a basic principle, high oil content (especially in pistachio kernels) encourages the tendency to self-heating.

Fat decomposition in pistachio nuts leads to the risk of self-heating and, ultimately, to a cargo fire.

Fat decomposition may proceed as follows:

by hydrolytic/enzymatic fat cleavage or

by oxidative fat cleavage

Hydrolytic/enzymatic fat cleavage
If the critical water content of the pistachio nuts is exceeded, this promotes hydrolytic/enzymatic fat cleavage. Fat-cleaving enzymes are activated by the elevated water content. The additional action of light and heat may accelerate this process. Free fatty acids sometimes have an unpleasant odor and taste. In the event of extended storage or improper cargo care, these cause the cargo to become rancid.

The free fatty acids formed are consumed by respiration processes in the pistachio nuts to form carbon dioxide and water, a process which is associated with considerable evolution of heat.

Self-heating of pistachio nuts is an extremely vigorous process, as the consumption of fatty acids by respiration processes is associated with a considerably greater evolution of heat than is the case with the respiration equation for carbohydrates.
Here too, as with cereals, the spoilage process proceeds in a type of chain reaction, because heat and water are formed by the fatty acids consumed by respiration, which in turn contribute to an intensification of the process.

The self-heating of pistachio nuts requires only a small seat of moisture, so that within just a few hours heating may occur at moist points for which weeks or months would be required in goods dry on shipment.

Fresh pistachio nuts with high water content tend in particular towards rapid self-heating and may also ignite. Self-heating of pistachio nuts leads not only to a reduction in the utility value of this product (rancid odor and taste) but also has a qualitative and quantitative effect on oil yield.
The color and bleach ability of the oils are also negatively affected. The oil obtained complicates refining of the crude oils in subsequent processing, because higher free fatty acid content makes decolonization substantially more difficult.

Hydrolytic/enzymatic fat cleavage and respiration may be limited by low temperatures; however, this may only be affected to a limited degree during transport. It is therefore important to ensure storage stability by complying with the limit values for the water content of the goods.

Oxidative fat cleavage
Food components frequently react with atmospheric oxygen in spoilage processes. Atmospheric oxygen may enter into an addition reaction with unsaturated fatty acids through the simultaneous assistance of light, heat and certain fat companion substances, and possibly also traces of heavy metals.
Rancidity caused by oxidative fat cleavage is particularly noticeable in the case of shelled pistachio nuts, because the shelling process results to a certain degree in exposure to atmospheric oxygen or to the steel parts of the ship or the container walls, if not carefully covered.
It is therefore absolutely essential to store pistachio nuts in the dark and to protect them from oxygen and metal parts, since otherwise they become brown-colored and develop a rancid odor and taste.

RF Odor

Active behavior	Pistachio nuts have a very slight, pleasant odor. If they are transported or stored for an extended period without ventilation, they spoil and release a strong odor.
Passive behavior	Pistachio nuts are sensitive to unpleasant and/or pungent odors.

 

RF contamination

Active behavior	Risk of contamination of other goods by fats and oils.
Passive behavior	Pistachio nuts are sensitive to dust, dirt, fats and oils.

RF Mechanical influences
Pistachio nuts are impact- and pressure-sensitive. They may suffer breakage. Excessive stack pressures must in particular be avoided.

RF Toxicity / Hazards to health
If ventilation has been inadequate (frost) or has failed owing to a defect, life-threatening CO₂ concentrations or O₂ shortages may arise.
Therefore, before anybody enters the hold, it must be ventilated and a gas measurement carried out. The TLV for CO2 concentration is 0.49 vol. %.

Danger: pistachio nuts may contain aflatoxin. The molds Aspergillums flatus and Aspergillums parasitic us produce the toxin aflatoxin, which may be present in the cargo as a result of an attack by the above-mentioned mold types.
In general, this is "country damage", i.e.

The toxin is already present in the pistachio nuts at the time of harvesting. As a rule, aflatoxin is only found in individual pistachio nuts.

If batches intended as a human foodstuff are affected by this toxin, the product can no longer be approved for human consumption.
Pistachio nuts affected by aflatoxin cannot readily be distinguished from the other nuts in a batch. The toxin may be detect.

RF Shrinkage/Shortage
Weight loss of up to 1% due to moisture loss may occur.

As pistachio nuts are a relatively valuable cargo, there is considerable risk of theft.

RF Toxicity / Hazards to health
Insect infestation is possible: mites, cockroaches, saw-toothed grain beetles, flour beetles, meal moths, dried fruit moths and rats and mice may attack pistachio nuts.

Pistachio nuts from the previous year's harvest have a particular tendency to beetle infestation.

The quarantine regulations of the country of destination must be complied with and a phytosanitary certificate and fumigation certificate may have to be enclosed with the shipping documents.

Information may be obtained from the phytosanitary authorities of the countries concerned.

Some useful information about pistachio